Аннотация

In recent times we can notice a large number of counterfeit fruit wines in the market as it is difficult to discover exogenous alcohols in them. This is due to the fact that while producing table fruit wines it is allowed to add cane or beet sugar during fermentation to provide necessary alcohol conditions. Our measurements were carried out with the help of the method “Détermination du rapport isotopique 13C/12C par spectrométrie de mass isotopique de l'éthanol du vin ou de l'éthanol obtenu par fermentation des moûts concentrés ou des moûts concentrés rectifies” OIV-MA-AS312-06. Analyzing Russian crops of fruit and berries in 2015, with the exception of pomegranate (Azerbaijan), we have obtained the following results: black currant - minus 25.75 ± 0.08‰, cherry - minus 25.62 ± 0.06‰, chokeberry - minus 26.13 ± 0.26‰, pear - minus 27.04 ± 0.06‰, plum - minus 26.24 ± 0.41‰, apple - minus 27.58 ± 0.54‰ and pomegranate - minus 28.21 ± 0.22‰. These results suggest the following conclusions: using exogenous alcohols derived from plants C3 - photosynthesis type leads to a slight change in isotopic characteristics of carbon ethanol in fruit wines, while adding sugars or alcohols from plants C4 - type leads to an increase of the isotope 13C, resulting in significant changes of the indicator δ13C . To establish significant differences of exogenous alcohols C3 - type introduced from the outside and obtained by fermentation of adding beet sugar, in some cases it is not enough to use the only one indicator δ13 C (‰). Therefore promising researches are connected with defining isotope ratios of other biophilic elements of fruit ethanol, namely, oxygen 18O/16O and hydrogen D/H.

Ключевые слова

fruit wine, ethanol, isotope mass spectrometry, stable isotopes, the ratio 13C/12C, isotopic characteristics

СПИСОК ЛИТЕРАТУРЫ

1. O’Leary M.Y. Carbon isotope fractionation in plants. Phytochemistry, 1981, vol. 20, no. 4, pp. 553-567.
2. Boutton T.W., Archer S.R., and Midwood A.J. Stable Isotopes in Ecosystem Science: Structure, Function and Dynamics of a Subtropical Savanna. Rapid Commun. Mass Spectrom, 1999, vol. 13, pp. 1263-1277.
3. Adami L., Dutra S.V., Marcon A.R., et al. Geographic origin of southern Brazilian wines by carbon and oxygen isotope analysis. Rapid Commun. Mass Spectrometry, 2010, vol. 24, pp. 2943-2948.
4. Ogrinc N., Kosir I.J., Kosjancic M., and Kidric J. Determination of Authenticy Regional Origin, and Vintage of Slovenian Wines using a Combination of IRMS and SNIF-NMR Analyses. J. Agric. Food Chem., 2001, vol. 49, pp. 1432-1440.
5. Guyon F., Douet C., Colas S., et al. Effect of Must concentration Techniques on Wine Isotopic Parameters. J. Agricul. Food Chem., 2006, vol. 54, pp. 9918-9923.
6. Dutra S.V., Adami L., Marcon A.R., et al. Characterization of wines according the geographical origin by analysis of isotopes and minerals and the influence of harvest on isotope values. Food Chem., 2013, vol. 141, pp. 2148-2153.
7. Martin G.J., Mazure M., Jouitteau C., et al. Characterization of the geographic origin of Bourdeaux wines by a combined use of isotopic and trace element measurements. American Journal of Enology and Viticulture, 1999, vol. 50, pp. 409-417.
8. Method OIV-MA-AS312-06: R2009. Determination by isotope ratio mass spectrometry 13С/12С of wine ethanol or that obtained through the fermentation of musts, concentrated musts or grape sugar. Compendium of international methods of analisis - OIV Ethanol.
9. Oganesyants L.A., Panasyuk A.L., Kuz'mina E.I., et al. Determining the nature of the carbon dioxide in sparkling wines and beverages. Beer and beverages, 2012, no. 2, pp. 20-21. (In Russian).
10. Zyakun A.M., Oganesyants L.A., Panasyuk A.L., Kuz'mina E.I., et al. Mass spectrometric analysis of the prevalence of isotopes 13С/12С in the grape plants and wine depending on climatic factors. Mass-Spektrometria, 2012, vol. 9, no. 1, pp. 16-21. (In Russian).
11. Oganesyants L.A., Panasyuk A.L, Kuz'mina E.I., et al. Determining the authenticity of cognacs on the basis of establishing the nature of the alcohol. Winemaking and Viticulture, 2012, no. 2, pp.14-15. (In Russian).
12. Oganesyants L., Panasyuk A., Kuzmina E., and Zyakun A. L`Influence de la situation geographique et des facteurs pédoclimatique sur le rapport d`isotopes 13C/12C dans le raisin et dans le vin. Le bulletin de l’OIV, 2012, vol. 85, no. 971-973, pp. 61-70.
13. Oganesyants L.A., Panasyuk A.L., Kuzmina E.I., and Zyakun A.M. The distribution of stable isotopes of the carbon in plants of grape and wine according to climate factors of district. Food Proccessing Industry, 2013, no. 1, pp. 12-15.
14. Oganesyants L.A., Panasyuk A.L., Kuz'mina E.I., and Zyakun A.M. Distribution of stable carbon isotopes in plants and grape wine depending on climatic factors. Food Industry, 2013, no. 2, pp. 28-31. (In Russian).
15. Oganesyants L.A., Panasyuk A.L., Kuzmina E.I., Zyakun A.M., et al. Mass spectrometric analysis of the 13C/12C abundance ratios in vine plants and wines depending on regional climate factors (Krasnodar krai and Rostov oblast, Russia). Journal of Analytical Chemistry, 2013, vol.68, no. 13, pp. 1136-1141.
16. Oganesyants L.A., Panasyuk A.L., Kuz'mina E.I., and Zyakun A.M. Isotopic characteristics of ethanol in wine from grapes grown in Russia. Winemaking and Viticulture, 2015, no. 4, pp. 8-12. (In Russian).
17. Bauer-Christoph C., Wachter H., Christoph N., Rossmann A., and Adam L. Assigment of raw material and authentication of spirits by gas chromatography, hydrogen- and carbon-isotope ratio measurements. Z. Lebensm Unter Forsch A, 1997, vol. 204, no. 6, pp. 445-452.
18. Winterova R., Mikulikova R., Mazác J., and Havelec P. Assessment of the Authenticity of Fruit Spirits by Gas Chromatography and Stable Isotope Ratio Analyses. Czech J. Food Sci., 2008, vol. 26, no. 5, pp. 368-375.